Perfluoropolyethers (PFPE) are a class of frequently used lubricants in space applications due to their high stability under demanding conditions. However, they are susceptible to aging, with the aging mechanism being dependent on the specific material combination and storage condition. A Lewis-acid-induced thermo-catalytic degradation mechanism is of concern, for example, under steel-on-steel sliding contact, and can be relevant for long-term storage (LTS). Accelerated aging experiments were performed on Fomblin® Z25 and Krytox™ 143AC to investigate thermal stability under the influence of iron(III) fluoride (FeF3) at elevated temperatures (180 °C, 200 °C, and 220 °C) up to a total duration of 2000 h. The degradation effects were monitored via selected analysis techniques: mass loss of the samples due to degradation and subsequent evaporation during aging, FTIR spectroscopy to investigate changes to the chemical structure, dynamic viscosity measurements for the investigation of a potential impact due to changes in molecular mass, and a ball-on-disc tribological test setup to obtain friction behavior of the aged lubricants. Distinct differences between the two types of PFPE lubricants regarding stability to thermo-catalytic degradation were found. Fomblin® Z25 was highly affected by the presence of FeF3 within the selected aging conditions, exhibiting high mass loss, a significant drop in dynamic viscosity, and an increased coefficient of friction due to degradation reactions.
Bibliographische NotizFunding Information:
This research work was performed at the Polymer Competence Center Leoben GmbH (PCCL, Austria) under a program of, and funded by, the European Space Agency (contract number 4000134572/21/NL/KML/rk). PCCL is funded by the Austrian Government and the State Governments of Styria, Upper and Lower Austria. However, the views expressed herein can in no way be taken to reflect the official opinion of the European Space Agency and are not intended to endorse particular technologies, companies, or products.
© 2023 by the authors.