Abstract
The adhesion of protective hard coatings to the substrate is one of the most important parameters that influence the performance of metal cutting tools. By a combination of high-resolution transmission electron microscopy and first principles modelling we determine the interface adhesion between a TiN hard coating and microstructural constituents of a high speed steel on an atomic level for the first time. Based on experimentally observed orientation relationships, multiple structures are studied for each interface and both interface cohesion and resistance to sliding are evaluated for MC and M 6C carbides as well as the martensitic matrix to TiN coating. We find that TiN coatings have high adhesion to MC carbides, while lower adhesion is present for M 6C and the martensitic matrix. Close agreement with experimental measurements validates this approach and suggests new strategies for developing steels with increased coating adhesion.
Originalsprache | Englisch |
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Aufsatznummer | 117439 |
Seitenumfang | 9 |
Fachzeitschrift | Acta materialia |
Jahrgang | 222.2022 |
Ausgabenummer | 1 January |
Frühes Online-Datum | 24 Okt. 2021 |
DOIs | |
Publikationsstatus | Veröffentlicht - 1 Jan. 2022 |
Bibliographische Notiz
Funding Information:The authors gratefully acknowledge the financial support under the scope of the COMET program within the K2 Center ?Integrated Computational Material, Process and Product Engineering (IC-MPPE)? (Project No. 859480). This program is supported by the Austrian Federal Ministries for Climate Action, Environment, Energy, Mobility, Innovation and Technology (BMK) and for Digital and Economic Affairs (BMDW), represented by the Austrian research funding association (FFG), and the federal states of Styria, Upper Austria and Tyrol. CzechNanoLab project LM2018110 funded by MEYS CR is gratefully acknowledged for the financial support of the measurements and sample fabrication at CEITEC Nano Research Infrastructure.
Funding Information:
The authors gratefully acknowledge the financial support under the scope of the COMET program within the K2 Center “Integrated Computational Material, Process and Product Engineering (IC-MPPE)” (Project No. 859480). This program is supported by the Austrian Federal Ministries for Climate Action, Environment, Energy, Mobility, Innovation and Technology (BMK) and for Digital and Economic Affairs (BMDW), represented by the Austrian research funding association (FFG), and the federal states of Styria, Upper Austria and Tyrol. CzechNanoLab project LM2018110 funded by MEYS CR is gratefully acknowledged for the financial support of the measurements and sample fabrication at CEITEC Nano Research Infrastructure.
Publisher Copyright:
© 2021