Hydrogen role in the valorization of integrated steelworks process off-gases through methane and methanol syntheses

Ismael Matino, Stefano Dettori, Antonella Zaccara, Alice Petrucciani, Vincenzo Iannino, Valentina Colla, Michael Bampaou, Kyriakos Panopoulos, Katharina Rechberger, Sebastian Kolb, Alexander Hauser, Philipp Wolf-Zöllner, Stéphane Haag, Nina Kieberger, Przemyslaw Rompalski

Publikation: Beitrag in FachzeitschriftArtikelForschungBegutachtung


The valorization of integrated steelworks process off-gases as feedstock for synthesizing methane and methanol is in line with European Green Deal challenges. However, this target can be generally achieved only through process off-gases enrichment with hydrogen and use of cutting-edge syntheses reactors coupled to advanced control systems. These aspects are addressed in the RFCS project i3upgrade and the central role of hydrogen was evident from the first stages of the project. First stationary scenario analyses showed that the required hydrogen amount is significant and existing renewable hydrogen production technologies are not ready to satisfy the demand in an economic perspective. The poor availability of low-cost green hydrogen as one of the main barriers for producing methane and methanol from process off-gases is further highlighted in the application of an ad-hoc developed dispatch controller for managing hydrogen intensified syntheses in integrated steelworks. The dispatch controller considers both economic and environmental impacts in the cost function and, although significant environmental benefits are obtainable by exploiting process off-gases in the syntheses, the current hydrogen costs highly affect the dispatch controller decisions. This underlines the need for big scale green hydrogen production processes and dedicated green markets for hydrogen-intensive industries, which would ensure easy access to this fundamental gas paving the way for a C-lean and more sustainable steel production.
FachzeitschriftMatériaux et techniques
PublikationsstatusElektronische Veröffentlichung vor Drucklegung. - 4 März 2022

Bibliographische Notiz

Funding Information:
Acknowledgments. The work described in this paper was developed within the project entitled “Integrated and intelligent upgrade of carbon sources through hydrogen addition for the steel industry, i3upgrade”) (GA No. 800659), which has received funding from the Research Fund for Coal and Steel of the European Union. The sole responsibility of the issues treated in this paper lies with the authors; the Commission is not responsible for any use that may be made of the information contained therein.

Publisher Copyright:
© 2022 I. Matino et al.


  • process-off gases valorization
  • green hydrogen use
  • methane and methanol syntheses
  • advanced control
  • steelmaking industry sustainability

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