Influence of hot liquid flowing water on Zeolite Y stability

Markus Latschka, B. Wellscheid, Raffael Rameshan, Tobias Rahphael Schöberl, Johannes Essmeister, Gernot Pacholik, F. Valentini, L. Balta, Andreas Limbeck, Christoph Rameshan, Hanspeter Kählig, Karin Föttinger

Publikation: Beitrag in FachzeitschriftArtikelForschungBegutachtung


Zeolite Y is used in a wide field of catalysis because of its high surface area and strong acidity. Since flowing water is present in many catalytic liquid phase reactions, its impact was investigated. For that, the zeolite Y was treated with water at 200 °C and 42 bar in a flow reactor. The resulting characterization showed strong structural changes at high water flows. The typical zeolite structure was almost completely lost, but an amorphous phase similar to the faujasite framework was formed. Due to this, the characteristic micropores were destroyed (d = 0.7 nm, volume was reduced from 0.18 to 0.01 cm3/g) and small mesopores were created (d = 2–3 nm, volume was increased from 0.25 to 0.51 cm3/g). As a result, the specific surface area was not greatly reduced and was still at around 250 m2/g. In addition, the amount of octahedrally coordinated EFAl increased from 54 to 70% and a γ-Al2O3 as well as a kaolinite phase was observed. The formed tetrahedrally coordinated EFAl is responsible for EFAl-OH groups, which are strong Brønsted acid sites. In general, the total acid sites of the zeolite Y were not strongly reduced and the ratio of Lewis to Brønsted acid sites slightly increased from 70:30% to 80:20%. For all Al species, the oxygen coordination was strongly distorted. After water treatment, on Si a large number of coordinated OSi and OAl groups were substituted with OH groups. The ratio of Si to Al decreased from 1 to 0.7, because Si was dissolved out of the zeolite by the water. On the surface, it was vice versa, there the Si accumulated (the Si/Al ratio increased from 0.2 to 0.8), presumably as silica gel.
FachzeitschriftMicroporous and Mesoporous Materials
Ausgabenummer15 April
PublikationsstatusVeröffentlicht - 15 Apr. 2023

Bibliographische Notiz

Funding Information:
The support of FFG (frontrunner project 879587) for the funding is gratefully acknowledged. This work was supported by the TU Wien and the Austrian Science Fund FWF (SFB “TACO” F-81). C. Rameshan acknowledges for funding by the European Research Council ( ERC ) under the Horizon Europe research and innovation programme, grant agreement no. 101068557/ERC—Proof of Concept Grant TUCAS-CO 2 . We acknowledge support by the NMR centre of the Faculty of Chemistry, University of Vienna . We thank Werner Artner and Klaudia Hradil from the X-ray center of TU Wien for the help with XRD and XRF measurements. We are thankful to Peter Weinberger for the possibility to measure ATR-IR spectroscopy in far-IR range. We acknowledge TU Wien Bibliothek for financial support provided by the Open Access Funding Programme.

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© 2023

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