TY - JOUR
T1 - Optimizing methane plasma pyrolysis for instant hydrogen and high-quality carbon production
AU - Daghagheleh, Oday
AU - Schenk, Johannes
AU - Zheng, Heng
AU - Zarl, Michael Andreas
AU - Farkas, Manuel
AU - Ernst, Daniel
AU - Kieush, Lina
AU - Lehner, Markus
AU - Kostoglou, Nikolaos
AU - Obenaus-Emler, Robert
N1 - Publisher Copyright: © 2024 The Author(s)
PY - 2024/7/14
Y1 - 2024/7/14
N2 - The European Green Deal has set a target for Europe to achieve net-zero greenhouse gas emissions by 2050, necessitating a transition to more sustainable energy sources. Hydrogen gas (H
2) has emerged as a promising solution, with methane pyrolysis presenting a viable method for its production. This study explores the optimization of methane plasma pyrolysis for hydrogen and high-quality carbon production. Employing a statistical approach by a design of experiment software, critical process parameters are systematically analyzed to predict their impact within a defined range. Additionally, the paper conducts comprehensive characterization of the solid carbon produced during pyrolysis using imaging, spectroscopic and elemental analysis, and gas sorption analysis methods. The experimental investigation was conducted using a thermal plasma reactor with several settings of influential parameters including methane gas (CH
4) content in the plasma gas, electric current, and arc length. The DC-transferred plasma arc is formed using a variable gas mixture of argon gas (Ar) and CH
4, with a constant flow rate of 5 Nl/min. Thirteen tests were designed, evaluating responses such as power input, process stability, and H
2 yield. The H
2 yield indicates the hydrogen produced from CH
4, with 100% representing total conversion. While the process exhibited inconstancy, attributed to reactor design constraints, a high H
2 yield of 67%–100% was achieved. The results indicate that a higher CH
4 content in the plasma gas and extended arc lengths disturb the plasma arc, hence reducing the H
2 yield. Increased power input, achieved through higher amperage levels, and a wider reaction zone eased by extending the arc length both led to an improved H
2 yield. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) revealed microstructural differences, with carbon samples from the filter exhibiting finer textures and carbon samples from the reactor larger sizes and dendritic particles. Raman spectroscopy confirmed crystalline graphitic-like structures with low defect concentrations, a finding supported by X-ray diffraction (XRD) analysis. Inductively coupled plasma mass spectroscopy (ICP-MS) analysis confirmed high-purity carbon with slight impurities from initial filter contamination. Brunauer-Emmett-Teller (BET) specific surface area calculations based on gas sorption analysis showed significant variations, with filter-collected samples exhibiting 40–170 m
2/g and reactor-collected ones showing 7–30 m
2/g.
AB - The European Green Deal has set a target for Europe to achieve net-zero greenhouse gas emissions by 2050, necessitating a transition to more sustainable energy sources. Hydrogen gas (H
2) has emerged as a promising solution, with methane pyrolysis presenting a viable method for its production. This study explores the optimization of methane plasma pyrolysis for hydrogen and high-quality carbon production. Employing a statistical approach by a design of experiment software, critical process parameters are systematically analyzed to predict their impact within a defined range. Additionally, the paper conducts comprehensive characterization of the solid carbon produced during pyrolysis using imaging, spectroscopic and elemental analysis, and gas sorption analysis methods. The experimental investigation was conducted using a thermal plasma reactor with several settings of influential parameters including methane gas (CH
4) content in the plasma gas, electric current, and arc length. The DC-transferred plasma arc is formed using a variable gas mixture of argon gas (Ar) and CH
4, with a constant flow rate of 5 Nl/min. Thirteen tests were designed, evaluating responses such as power input, process stability, and H
2 yield. The H
2 yield indicates the hydrogen produced from CH
4, with 100% representing total conversion. While the process exhibited inconstancy, attributed to reactor design constraints, a high H
2 yield of 67%–100% was achieved. The results indicate that a higher CH
4 content in the plasma gas and extended arc lengths disturb the plasma arc, hence reducing the H
2 yield. Increased power input, achieved through higher amperage levels, and a wider reaction zone eased by extending the arc length both led to an improved H
2 yield. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) revealed microstructural differences, with carbon samples from the filter exhibiting finer textures and carbon samples from the reactor larger sizes and dendritic particles. Raman spectroscopy confirmed crystalline graphitic-like structures with low defect concentrations, a finding supported by X-ray diffraction (XRD) analysis. Inductively coupled plasma mass spectroscopy (ICP-MS) analysis confirmed high-purity carbon with slight impurities from initial filter contamination. Brunauer-Emmett-Teller (BET) specific surface area calculations based on gas sorption analysis showed significant variations, with filter-collected samples exhibiting 40–170 m
2/g and reactor-collected ones showing 7–30 m
2/g.
KW - Carbon
KW - Green energy
KW - Hydrogen production
KW - Methane pyrolysis
KW - Natural gas pyrolysis
KW - Sustainability
KW - Thermal plasma
KW - Turquoise hydrogen
UR - http://www.scopus.com/inward/record.url?scp=85198305027&partnerID=8YFLogxK
U2 - 10.1016/j.ijhydene.2024.07.129
DO - 10.1016/j.ijhydene.2024.07.129
M3 - Article
SN - 0360-3199
VL - 79.2024
SP - 1406
EP - 1417
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
IS - 19 August
ER -