Strategies for the Upgrade of a TBZC Product (Tetra Basic Zinc Chloride) by Selective Removal of the Impurity Chlorine

Lukas Höber; Rana Mohamed Abdelmonnem Ahmed; Thomas Hofbauer; Stefan Steinlechner

doi:10.1007/978-3-030-92381-5_10

Strategies for the Upgrade of a TBZC Product (Tetra Basic Zinc Chloride) by Selective Removal of the Impurity Chlorine

Lukas Höber, Rana Mohamed Abdelmonnem Ahmed, Thomas Hofbauer, Stefan Steinlechner

Lehrstuhl für Nichteisenmetallurgie (520)

Andritz AG, Wien

Publikation: Beitrag in Buch/Bericht/Konferenzband › Beitrag in Konferenzband

Abstract

When recycling materials containing zinc in hydrochloric acid processes, the precipitation of zinc can lead to the formation of various compounds which can be assigned to the group of zinc hydroxide chlorides. This paper compares different approaches for the selective removal of chlorine from tetra basic zinc chloride to obtain a cleaned zinc product. The removal of chlorine via soda leaching at atmospheric conditions as well as under overpressure in an autoclave was investigated. Furthermore, concepts were considered in which the chlorine can be evaporated as a compound and thus separated via selective temperature and atmospheric control. Thereby, a focus is on the simulation of pyrohydrolysis and clinkering for the separation of chlorine via gaseous compounds whereby zinc remains and can be brought to further processing. The simulations with multivariant parameters are carried out using the thermochemical calculation software package FactSage.

Originalsprache	Englisch
Titel	TMS 2022
Untertitel	151st Annual Meeting and Exhibition Supplemental Proceedings
Herausgeber (Verlag)	Springer Cham
Seiten	95-108
Seitenumfang	14
Band	151
ISBN (elektronisch)	978-3-030-92381-5
ISBN (Print)	978-3-030-92380-8
DOIs	https://doi.org/10.1007/978-3-030-92381-5_10
Publikationsstatus	Veröffentlicht - 7 Feb. 2022
Veranstaltung	151st Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2022 - Anaheim, USA / Vereinigte Staaten Dauer: 27 Feb. 2022 → 3 März 2022

Publikationsreihe

Name	Minerals, Metals and Materials Series
ISSN (Print)	2367-1181
ISSN (elektronisch)	2367-1696

Konferenz

Konferenz	151st Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2022
Land/Gebiet	USA / Vereinigte Staaten
Ort	Anaheim
Zeitraum	27/02/22 → 3/03/22

Bibliographische Notiz

Funding Information:
This work was funded by the Christian Doppler Research Association, the Austrian Federal Ministry for Digital and Economic Affairs, and the National Foundation for Research, Technology, and Development.

Publisher Copyright:
© 2022, The Minerals, Metals & Materials Society.

Zugriff auf Dokument

10.1007/978-3-030-92381-5_10

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Verknüpfung zur Publikation in Scopus

Dieses zitieren

Höber, L., Mohamed Abdelmonnem Ahmed, R., Hofbauer, T., & Steinlechner, S. (2022). Strategies for the Upgrade of a TBZC Product (Tetra Basic Zinc Chloride) by Selective Removal of the Impurity Chlorine. in TMS 2022: 151st Annual Meeting and Exhibition Supplemental Proceedings (Band 151, S. 95-108). (Minerals, Metals and Materials Series). Springer Cham. https://doi.org/10.1007/978-3-030-92381-5_10

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abstract = "When recycling materials containing zinc in hydrochloric acid processes, the precipitation of zinc can lead to the formation of various compounds which can be assigned to the group of zinc hydroxide chlorides. This paper compares different approaches for the selective removal of chlorine from tetra basic zinc chloride to obtain a cleaned zinc product. The removal of chlorine via soda leaching at atmospheric conditions as well as under overpressure in an autoclave was investigated. Furthermore, concepts were considered in which the chlorine can be evaporated as a compound and thus separated via selective temperature and atmospheric control. Thereby, a focus is on the simulation of pyrohydrolysis and clinkering for the separation of chlorine via gaseous compounds whereby zinc remains and can be brought to further processing. The simulations with multivariant parameters are carried out using the thermochemical calculation software package FactSage.",

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Höber, L, Mohamed Abdelmonnem Ahmed, R, Hofbauer, T & Steinlechner, S 2022, Strategies for the Upgrade of a TBZC Product (Tetra Basic Zinc Chloride) by Selective Removal of the Impurity Chlorine. in TMS 2022: 151st Annual Meeting and Exhibition Supplemental Proceedings. Bd. 151, Minerals, Metals and Materials Series, Springer Cham, S. 95-108, 151st Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2022, Anaheim, USA / Vereinigte Staaten, 27/02/22. https://doi.org/10.1007/978-3-030-92381-5_10

Strategies for the Upgrade of a TBZC Product (Tetra Basic Zinc Chloride) by Selective Removal of the Impurity Chlorine. / Höber, Lukas; Mohamed Abdelmonnem Ahmed, Rana; Hofbauer, Thomas et al.
TMS 2022: 151st Annual Meeting and Exhibition Supplemental Proceedings. Band 151 Springer Cham, 2022. S. 95-108 (Minerals, Metals and Materials Series).

Publikation: Beitrag in Buch/Bericht/Konferenzband › Beitrag in Konferenzband

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AU - Höber, Lukas

AU - Mohamed Abdelmonnem Ahmed, Rana

AU - Hofbauer, Thomas

AU - Steinlechner, Stefan

PY - 2022/2/7

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N2 - When recycling materials containing zinc in hydrochloric acid processes, the precipitation of zinc can lead to the formation of various compounds which can be assigned to the group of zinc hydroxide chlorides. This paper compares different approaches for the selective removal of chlorine from tetra basic zinc chloride to obtain a cleaned zinc product. The removal of chlorine via soda leaching at atmospheric conditions as well as under overpressure in an autoclave was investigated. Furthermore, concepts were considered in which the chlorine can be evaporated as a compound and thus separated via selective temperature and atmospheric control. Thereby, a focus is on the simulation of pyrohydrolysis and clinkering for the separation of chlorine via gaseous compounds whereby zinc remains and can be brought to further processing. The simulations with multivariant parameters are carried out using the thermochemical calculation software package FactSage.

AB - When recycling materials containing zinc in hydrochloric acid processes, the precipitation of zinc can lead to the formation of various compounds which can be assigned to the group of zinc hydroxide chlorides. This paper compares different approaches for the selective removal of chlorine from tetra basic zinc chloride to obtain a cleaned zinc product. The removal of chlorine via soda leaching at atmospheric conditions as well as under overpressure in an autoclave was investigated. Furthermore, concepts were considered in which the chlorine can be evaporated as a compound and thus separated via selective temperature and atmospheric control. Thereby, a focus is on the simulation of pyrohydrolysis and clinkering for the separation of chlorine via gaseous compounds whereby zinc remains and can be brought to further processing. The simulations with multivariant parameters are carried out using the thermochemical calculation software package FactSage.

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Höber L, Mohamed Abdelmonnem Ahmed R, Hofbauer T, Steinlechner S. Strategies for the Upgrade of a TBZC Product (Tetra Basic Zinc Chloride) by Selective Removal of the Impurity Chlorine. in TMS 2022: 151st Annual Meeting and Exhibition Supplemental Proceedings. Band 151. Springer Cham. 2022. S. 95-108. (Minerals, Metals and Materials Series). doi: 10.1007/978-3-030-92381-5_10