TY - JOUR
T1 - Design of high-strength martensitic steels by novel mixed-metal nanoprecipitates for high toughness and suppressed hydrogen embrittlement
AU - Moshtaghi, Masoud
AU - Maawad, Emad
AU - Bendo, Artenis
AU - Krause, Andreas
AU - Todt, Juraj
AU - Keckes, Jozef
AU - Safyari, Mahdieh
N1 - Publisher Copyright: © 2023 The Authors
PY - 2023/9/14
Y1 - 2023/9/14
N2 - To obtain a fundamental understanding of mechanisms of hydrogen embrittlement (HE) and its prevention in advanced high-strength steels containing novel nanoscale mixed-metal precipitates, it is necessary to study local microstructure, H trapping, and crack path with new multiscale experimental and simulation approach. Spatially resolved hydrogen mapping via SKPFM is used together with investigation of the crack path using high-resolution EBSD and HMPT, and global trapping behavior of the alloys by TDS. These results are combined with newly introduced method to elucidate real-time distribution of hydrogen in the alloy using high-energy synchrotron X-ray diffraction (HES-XRD). Mixed-metal precipitates improves HE resistance of the alloy, due to nature of the trapping sites, e.g. irreversible H-trapping by carbon vacancies inside novel nanoprecipitates and high total length of PAGBs. This is because of lower possibility of build-up of critical local hydrogen content at PAGBs for intergranular hydrogen-assisted cracking due to hydrogen-enhanced decohesion mechanism. Less weakly trapped hydrogen also reduces frequency of dislocation activation and enhanced dislocation slip in {0 1 1} slip plane due to hydrogen-enhanced localized plasticity in regions with affinity for transgranular hydrogen-assisted cracking at lower local hydrogen content. Direct evidence of carbon vacancies in novel nanoprecipitates is observed for the first time via HAADF-STEM.
AB - To obtain a fundamental understanding of mechanisms of hydrogen embrittlement (HE) and its prevention in advanced high-strength steels containing novel nanoscale mixed-metal precipitates, it is necessary to study local microstructure, H trapping, and crack path with new multiscale experimental and simulation approach. Spatially resolved hydrogen mapping via SKPFM is used together with investigation of the crack path using high-resolution EBSD and HMPT, and global trapping behavior of the alloys by TDS. These results are combined with newly introduced method to elucidate real-time distribution of hydrogen in the alloy using high-energy synchrotron X-ray diffraction (HES-XRD). Mixed-metal precipitates improves HE resistance of the alloy, due to nature of the trapping sites, e.g. irreversible H-trapping by carbon vacancies inside novel nanoprecipitates and high total length of PAGBs. This is because of lower possibility of build-up of critical local hydrogen content at PAGBs for intergranular hydrogen-assisted cracking due to hydrogen-enhanced decohesion mechanism. Less weakly trapped hydrogen also reduces frequency of dislocation activation and enhanced dislocation slip in {0 1 1} slip plane due to hydrogen-enhanced localized plasticity in regions with affinity for transgranular hydrogen-assisted cracking at lower local hydrogen content. Direct evidence of carbon vacancies in novel nanoprecipitates is observed for the first time via HAADF-STEM.
UR - http://www.scopus.com/inward/record.url?scp=85171734543&partnerID=8YFLogxK
U2 - 10.1016/j.matdes.2023.112323
DO - 10.1016/j.matdes.2023.112323
M3 - Article
SN - 0264-1275
VL - 234.2023
JO - Materials & design
JF - Materials & design
IS - October
M1 - 112323
ER -