Selective Recovery of PGMs and Cerium by a Hydrochloric Leaching Process for Automotive Catalysts

Stefan Steinlechner

Selective Recovery of PGMs and Cerium by a Hydrochloric Leaching Process for Automotive Catalysts

Chair of Nonferrous Metallurgy (520)

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

The nowadays common recycling of selected platinum group metals from catalysts, namely platinum, palladium, and rhodium, typically takes place in course of a pyrometallurgical processing. In course of that, the PGMs are dissolved in a collector metal, such as nickel or iron, while in parallel the whole
monolith and the wash coat on top of the ceramic carrier is liquified and transferred to the slag phase. As a result, the utilized rare-earth of the wash coat, mainly cerium, is not recovered and gets diluted by other slag
components. Therefore, the present paper introduces an innovative recycling process based on hydrochloric leaching utilizing H2O2 as an oxidation agent for redox potential adjustment. Compared to common pyrometallurgical catalyst recycling technologies the hydrometallurgical route offers additionally the recovery of cerium as a product while in the same moment the solution can be reused and a remaining cleaned ceramic material is left behind as an additional by-product.

Original language	English
Title of host publication	Proceedings of the 59th Annual Conference of Metallurgists
Place of Publication	Canada
Publisher	The Canadian Institute of Mining, Metallurgy and Petroleum Engineering
ISBN (Electronic)	978-1-926872-47-6
ISBN (Print)	978-1-926872-47-6
Publication status	Published - 27 Aug 2020

SELECTIVE RECOVERY OF PGMS AND CERIUM BY A HYDROCHLORIC LEACHING PROCESS FOR AUTOMOTIVE CATALYSTS
Stefan Steinlechner (Speaker)
27 Aug 2020
Activity: Talk or presentation › Oral presentation

Cite this

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title = "Selective Recovery of PGMs and Cerium by a Hydrochloric Leaching Process for Automotive Catalysts",

abstract = "The nowadays common recycling of selected platinum group metals from catalysts, namely platinum, palladium, and rhodium, typically takes place in course of a pyrometallurgical processing. In course of that, the PGMs are dissolved in a collector metal, such as nickel or iron, while in parallel the wholemonolith and the wash coat on top of the ceramic carrier is liquified and transferred to the slag phase. As a result, the utilized rare-earth of the wash coat, mainly cerium, is not recovered and gets diluted by other slagcomponents. Therefore, the present paper introduces an innovative recycling process based on hydrochloric leaching utilizing H2O2 as an oxidation agent for redox potential adjustment. Compared to common pyrometallurgical catalyst recycling technologies the hydrometallurgical route offers additionally the recovery of cerium as a product while in the same moment the solution can be reused and a remaining cleaned ceramic material is left behind as an additional by-product.",

author = "Stefan Steinlechner",

year = "2020",

month = aug,

day = "27",

language = "English",

isbn = "978-1-926872-47-6",

booktitle = "Proceedings of the 59th Annual Conference of Metallurgists",

publisher = "The Canadian Institute of Mining, Metallurgy and Petroleum Engineering ",

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TY - GEN

T1 - Selective Recovery of PGMs and Cerium by a Hydrochloric Leaching Process for Automotive Catalysts

AU - Steinlechner, Stefan

PY - 2020/8/27

Y1 - 2020/8/27

N2 - The nowadays common recycling of selected platinum group metals from catalysts, namely platinum, palladium, and rhodium, typically takes place in course of a pyrometallurgical processing. In course of that, the PGMs are dissolved in a collector metal, such as nickel or iron, while in parallel the wholemonolith and the wash coat on top of the ceramic carrier is liquified and transferred to the slag phase. As a result, the utilized rare-earth of the wash coat, mainly cerium, is not recovered and gets diluted by other slagcomponents. Therefore, the present paper introduces an innovative recycling process based on hydrochloric leaching utilizing H2O2 as an oxidation agent for redox potential adjustment. Compared to common pyrometallurgical catalyst recycling technologies the hydrometallurgical route offers additionally the recovery of cerium as a product while in the same moment the solution can be reused and a remaining cleaned ceramic material is left behind as an additional by-product.

AB - The nowadays common recycling of selected platinum group metals from catalysts, namely platinum, palladium, and rhodium, typically takes place in course of a pyrometallurgical processing. In course of that, the PGMs are dissolved in a collector metal, such as nickel or iron, while in parallel the wholemonolith and the wash coat on top of the ceramic carrier is liquified and transferred to the slag phase. As a result, the utilized rare-earth of the wash coat, mainly cerium, is not recovered and gets diluted by other slagcomponents. Therefore, the present paper introduces an innovative recycling process based on hydrochloric leaching utilizing H2O2 as an oxidation agent for redox potential adjustment. Compared to common pyrometallurgical catalyst recycling technologies the hydrometallurgical route offers additionally the recovery of cerium as a product while in the same moment the solution can be reused and a remaining cleaned ceramic material is left behind as an additional by-product.

M3 - Conference contribution

SN - 978-1-926872-47-6

BT - Proceedings of the 59th Annual Conference of Metallurgists

PB - The Canadian Institute of Mining, Metallurgy and Petroleum Engineering

CY - Canada

ER -

Selective Recovery of PGMs and Cerium by a Hydrochloric Leaching Process for Automotive Catalysts

Abstract

Activities

SELECTIVE RECOVERY OF PGMS AND CERIUM BY A HYDROCHLORIC LEACHING PROCESS FOR AUTOMOTIVE CATALYSTS

Cite this